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At the age of twenty-one he was promoted to a professorship.
On 22 February, 1672, he was elevated to the cardinalate by his relative Clement X.
The only reproach made against his administration is that his simplicity and child-like confidence exposed him to the wiles of some unscrupulous persons who abused his confidence.
Cardinal Orsini had already taken part in four conclaves, when Innocent XIII died in March, 1724; and in all he had acted in the spirit of the zelanti .
His first concern as pope was to enforce rigidly ecclesiastical discipline .
As cardinal he adhered strictly to the observance of the rule of his order, and never laid aside his habit.
At a provincial Roman Lateran synod held in 1725, he required an unqualified acceptance of the Bull Unigenitus and through his efforts Cardinal de Noailles, Archbishop of Paris, was led to accept it in 1728.